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Abla Zouai, Yasmine Ait Ouaissa, Souad Bouafia, Malika Chabani, Nor El Houda Madi
Laboratory of Reaction Engineering, Faculty of Process Engineering and Mechanical Engineering, U.S.T.H.B a, Algeria
https://doi.org/10.5004/ic202421
ABSTRACT
This study examines the effectiveness of two electrochemical processes: electro-Fenton and electrocoagulation, in the degradation of pharmaceutical contaminants nystatin and atenolol. Batch-mode experiments were conducted using iron and aluminum electrodes for the electrocoagulation process to assess their performance. The findings revealed that electrocoagulation (EC) was highly efficient for nystatin degradation, achieving a removal rate of approximately 99% under optimal conditions: neutral pH and an initial concentration of 2.69 × 10–5 mol/L with aluminum electrodes. Conversely, the EC process proved ineffective for Atenolol degradation, showing low removal efficiency with both iron and aluminum electrodes. To address this limitation, the electro-Fenton process was implemented, resulting in a maximum degradation rate of 90% under optimal conditions: an initial pH of 3, a hydrogen peroxide (H2O2) concentration of 8 mM, a current intensity of 0.25 A, and an initial solution concentration of 1.87 × 10–5 mol/L (5 mg/L).
Keywords: Electrocoagulation; Electro-Fenton; Nystatin; Atenolol
Abla Zouai, Yasmine Ait Ouaissa, Souad Bouafia, Malika Chabani, Nor El Houda Madi
Laboratory of Reaction Engineering, Faculty of Process Engineering and Mechanical Engineering, U.S.T.H.B a, Algeria
https://doi.org/10.5004/ic202421
ABSTRACT
This study examines the effectiveness of two electrochemical processes: electro-Fenton and electrocoagulation, in the degradation of pharmaceutical contaminants nystatin and atenolol. Batch-mode experiments were conducted using iron and aluminum electrodes for the electrocoagulation process to assess their performance. The findings revealed that electrocoagulation (EC) was highly efficient for nystatin degradation, achieving a removal rate of approximately 99% under optimal conditions: neutral pH and an initial concentration of 2.69 × 10–5 mol/L with aluminum electrodes. Conversely, the EC process proved ineffective for Atenolol degradation, showing low removal efficiency with both iron and aluminum electrodes. To address this limitation, the electro-Fenton process was implemented, resulting in a maximum degradation rate of 90% under optimal conditions: an initial pH of 3, a hydrogen peroxide (H2O2) concentration of 8 mM, a current intensity of 0.25 A, and an initial solution concentration of 1.87 × 10–5 mol/L (5 mg/L).
Keywords: Electrocoagulation; Electro-Fenton; Nystatin; Atenolol