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Assia Mansouri1, Nadia Bendjaballah-Lalaoui1, Sarah Medjbar2
1Laboratoire Chimie des Matériaux, Catalyse et Environnent, Université des sciences et de la technologie Houari Boumediene, BP 32, El Alia, Bab Ezzouar, 16111 Algiers, Algeria
2Centre de Recherche Nucléaire de Draria CRND, Algiers, Algeria
https://doi.org/10.5004/ic202410
ABSTRACT
In this study, a nanocomposite consisting of iron-doped titanium dioxide (FeTiO2) and spinel NiFe2O4 were employed to enhance dye removal using the advanced oxidative process H2O2/UV. The co-precipitation method was used to synthesize both FeTiO2 and spinel, followed by characterization using X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) analysis. To evaluate their efficiency as photocatalysts, the materials were tested under UV light irradiation for the degradation of Rhodamine B in water. Kinetic studies revealed that the reaction followed pseudo-first-order kinetics, with a rate constant of 6.95×10–3 min–1 and degradation efficiencies of 68.57%, 67.21%, and 74.18% for NiFe2O4, FeTiO2-Im, and FeTiO2-SG, respectively. FeTiO2-SG exhibited superior photocatalytic performance compared to spinel for the degradation of Rhodamine B, suggesting that FeTiO2 is an efficient photocatalyst for the decolorization of Rhodamine B.
Keywords: Rhodamine B; Photo-Fenton process; Dye; Photodegradation
Assia Mansouri1, Nadia Bendjaballah-Lalaoui1, Sarah Medjbar2
1Laboratoire Chimie des Matériaux, Catalyse et Environnent, Université des sciences et de la technologie Houari Boumediene, BP 32, El Alia, Bab Ezzouar, 16111 Algiers, Algeria
2Centre de Recherche Nucléaire de Draria CRND, Algiers, Algeria
https://doi.org/10.5004/ic202410
ABSTRACT
In this study, a nanocomposite consisting of iron-doped titanium dioxide (FeTiO2) and spinel NiFe2O4 were employed to enhance dye removal using the advanced oxidative process H2O2/UV. The co-precipitation method was used to synthesize both FeTiO2 and spinel, followed by characterization using X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) analysis. To evaluate their efficiency as photocatalysts, the materials were tested under UV light irradiation for the degradation of Rhodamine B in water. Kinetic studies revealed that the reaction followed pseudo-first-order kinetics, with a rate constant of 6.95×10–3 min–1 and degradation efficiencies of 68.57%, 67.21%, and 74.18% for NiFe2O4, FeTiO2-Im, and FeTiO2-SG, respectively. FeTiO2-SG exhibited superior photocatalytic performance compared to spinel for the degradation of Rhodamine B, suggesting that FeTiO2 is an efficient photocatalyst for the decolorization of Rhodamine B.
Keywords: Rhodamine B; Photo-Fenton process; Dye; Photodegradation